Insights into the Coordination Chemistry of Phosphonate Derivatives of Heteropolyoxotungstates

Richard Villanneau (1, 2) , David Racimor (3) , Elisabeth Messner-Henning (1, 2) , Hélène Rousselière (4) , Sébastien Picart (5) , René Thouvenot (6) , Anna Proust (2, 1)

1 E-POM - Edifices PolyMétalliques
2 IPCM - Institut Parisien de Chimie Moléculaire
3 IPCM - Institut Parisien de Chimie Moléculaire
4 CIM2 - Laboratoire de Chimie Inorganique et Matériaux Moléculaires
5 LCA - Laboratoire de Chimie des Actinides
6 CIM2 - Laboratoire de Chimie Inorganique et Matériaux Moléculaires

The coordination properties of vacant bisphosphonate derivatives of polyoxometalates, with easily tunable functions, have been explored. The preparation and crystallographic structure of their La3+ and Zr4+ complexes are described herein.

Domaines: Chimie

Richard Villanneau, David Racimor, Elisabeth Messner-Henning, Hélène Rousselière, Sébastien Picart, et al.. Insights into the Coordination Chemistry of Phosphonate Derivatives of Heteropolyoxotungstates. Inorganic Chemistry, 2010, 50 (4), pp.1164-1166. ⟨10.1021/ic102223w⟩. ⟨hal-04564856⟩